Spain - Primera Division - Real Madrid (i think this team under lead of Mourinho will win title again this season, even they played 1-1 versus Valencia in first round, while their hottest opponent won versus Sosiedad with 5-1)
England - Premier League - Man City (Today they won hardly versus Southampton, while Chelsea won versus Wigan so easily. I'm fan of liverpool, yes, they failed hardly, but i think that is gonna be hotter in 2nd round, facing Man City. Arsenal failed, but not as Liverpool, just draw. MU didnt played their first match vs everton yet, but my opinion it will be draw.
Italy - Scudeto - Milan (There is not started season yet, but my thoughts go on Milan, and if they lost or sold some players, i think they have pottential, and will win this upcoming season)
Germany - Bundesliga - Bayern M (Previous season they lost title from BD, but i think this time is time for revenge, and hope they will get that.)